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Molecular structures of the pentaphenylcyclopentadienyl iron complexes [(C(5)Ph(5))Fe(CO)(2) R] (R = Me, Ph, iPr and Bu)
The Pd(II)-catalysed reaction of [(C(5)Ph(5))Fe(CO)(2)Br] with Grignard compounds RMgX or butyl lithium gave the iron alkyl/aryl complexes [(C(5)Ph(5))Fe(CO)(2) R] (R = Me, Ph, iPr and Bu) in 59–73% yield, namely, dicarbonylmethyl(η(5)-pentaphenylcyclopentadienyl)iron, [Fe(CH(3))(C(35)H(2...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8254530/ https://www.ncbi.nlm.nih.gov/pubmed/34216442 http://dx.doi.org/10.1107/S2053229621006057 |