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Mol­ecular structures of the penta­phenyl­cyclo­penta­dienyl iron com­plexes [(C(5)Ph(5))Fe(CO)(2) R] (R = Me, Ph, iPr and Bu)

The Pd(II)-catalysed reaction of [(C(5)Ph(5))Fe(CO)(2)Br] with Grignard com­pounds RMgX or butyl lithium gave the iron alk­yl/aryl com­plexes [(C(5)Ph(5))Fe(CO)(2) R] (R = Me, Ph, iPr and Bu) in 59–73% yield, namely, di­carbonyl­meth­yl(η(5)-penta­phenyl­cyclo­penta­dien­yl)iron, [Fe(CH(3))(C(35)H(2...

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Detalles Bibliográficos
Autores principales: Sünkel, Karlheinz, Klein-Hessling, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8254530/
https://www.ncbi.nlm.nih.gov/pubmed/34216442
http://dx.doi.org/10.1107/S2053229621006057