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Ensemble effects in Cu/Au ultrasmall nanoparticles control the branching point for C1 selectivity during CO(2) electroreduction

Bimetallic catalysts provide opportunities to overcome scaling laws governing selectivity of CO(2) reduction (CO(2)R). Cu/Au nanoparticles show promise for CO(2)R, but Au surface segregation on particles with sizes ≥7 nm prevent investigation of surface atom ensembles. Here we employ ultrasmall (2 n...

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Detalles Bibliográficos
Autores principales: Shang, Hongyu, Kim, Dongjoon, Wallentine, Spencer K., Kim, Minkyu, Hofmann, Daniel M., Dasgupta, Runiya, Murphy, Catherine J., Asthagiri, Aravind, Baker, L. Robert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8261774/
https://www.ncbi.nlm.nih.gov/pubmed/34276944
http://dx.doi.org/10.1039/d1sc02602j