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Insertion of Phosphenium Ions into a Bicyclo[1.1.0]Tetraphosphabutane Iron Complex

By reacting [{Cp‴Fe(CO)(2)}(2)(µ,η(1:1)-P(4))] (1) with in situ generated phosphenium ions [Ph(2)P][A] ([A](−) = [OTf](−) = [O(3)SCF(3)](−), [PF(6)](−)), a mixture of two main products of the composition [{Cp‴Fe(CO)(2)}(2)(µ,η(1:1)-P(5)(C(6)H(5))(2))][PF(6)] (2a and 3a) could be identified by extens...

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Detalles Bibliográficos
Autores principales: Weber, Martin, Balázs, Gábor, Virovets, Alexander V., Peresypkina, Eugenia, Scheer, Manfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8272002/
https://www.ncbi.nlm.nih.gov/pubmed/34206902
http://dx.doi.org/10.3390/molecules26133920