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Insertion of Phosphenium Ions into a Bicyclo[1.1.0]Tetraphosphabutane Iron Complex
By reacting [{Cp‴Fe(CO)(2)}(2)(µ,η(1:1)-P(4))] (1) with in situ generated phosphenium ions [Ph(2)P][A] ([A](−) = [OTf](−) = [O(3)SCF(3)](−), [PF(6)](−)), a mixture of two main products of the composition [{Cp‴Fe(CO)(2)}(2)(µ,η(1:1)-P(5)(C(6)H(5))(2))][PF(6)] (2a and 3a) could be identified by extens...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8272002/ https://www.ncbi.nlm.nih.gov/pubmed/34206902 http://dx.doi.org/10.3390/molecules26133920 |