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A 3D MOF based on Adamantoid Tetracopper(II) and Aminophosphine Oxide Cages: Structural Features and Magnetic and Catalytic Properties

[Image: see text] This work describes an unexpected generation of a new 3D metal–organic framework (MOF), [Cu(4)(μ-Cl)(6)(μ(4)-O)Cu(OH)(2)(μ-PTA=O)(4)](n)·2nCl-EtOH·2.5nH(2)O, from copper(II) chloride and 1,3,5-triaza-7-phosphaadamantane 7-oxide (PTA=O). The obtained product is composed of diamandoi...

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Detalles Bibliográficos
Autores principales: Śliwa, Ewelina I., Nesterov, Dmytro S., Kirillova, Marina V., Kłak, Julia, Kirillov, Alexander M., Smoleński, Piotr
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8277165/
https://www.ncbi.nlm.nih.gov/pubmed/34121384
http://dx.doi.org/10.1021/acs.inorgchem.1c00868