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Rhenium Corrole Dimers: Electrochemical Insights into the Nature of the Metal–Metal Quadruple Bond

[Image: see text] The interaction of free-base triarylcorroles with Re(2)(CO)(10) in 1,2-dichlorobenzene in the presence of 2,6-lutidine at 180 °C under strict anerobic conditions afforded approximately 10% yields of rhenium corrole dimers. The compounds exhibited diamagnetic (1)H NMR spectra consis...

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Detalles Bibliográficos
Autores principales: Alemayehu, Abraham B., McCormick-McPherson, Laura J., Conradie, Jeanet, Ghosh, Abhik
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8278387/
https://www.ncbi.nlm.nih.gov/pubmed/33998801
http://dx.doi.org/10.1021/acs.inorgchem.1c00986