Atropisomeric Properties of N-Acyl/N-Sulfonyl 5H-Dibenzo[b,d]azepin-7(6H)-ones

[Image: see text] The stereochemistry of N-acyl/N-sulfonyl 5H-dibenzo[b,d]azepin-7(6H)-ones (I, II) was examined in detail by freezing the conformation with a methyl group at the C-4 of dibenzoazepine. Because the two axes (axis 1, axis 2) move together concertedly, I and II exist only as a pair of...

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Detalles Bibliográficos
Autores principales: Namba, Takuya, Hotta, Mayuno, Tabata, Hidetsugu, Makino, Kosho, Oshitari, Tetsuta, Natsugari, Hideaki, Takahashi, Hideyo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8279494/
https://www.ncbi.nlm.nih.gov/pubmed/33998234
http://dx.doi.org/10.1021/acs.joc.1c00594

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8279494/
https://www.ncbi.nlm.nih.gov/pubmed/33998234
http://dx.doi.org/10.1021/acs.joc.1c00594

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