Mechanism and Origins of Stereoselectivity of the Aldol-Tishchenko Reaction of Sulfinimines

[Image: see text] Density functional theory computations have elucidated the mechanism and origins of stereoselectivity in McGlacken’s aldol-Tishchenko reaction for the diastereoselective synthesis of 1,3-amino alcohols using Ellman’s t-butylsulfinimines as chiral auxiliaries. Variations of stereoch...

Descripción completa

Detalles Bibliográficos
Autores principales: Turlik, Aneta, Ando, Kaori, Mackey, Pamela, Alcock, Emma, Light, Mark, McGlacken, Gerard P., Houk, K. N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8279497/
https://www.ncbi.nlm.nih.gov/pubmed/33586983
http://dx.doi.org/10.1021/acs.joc.0c02862

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8279497/
https://www.ncbi.nlm.nih.gov/pubmed/33586983
http://dx.doi.org/10.1021/acs.joc.0c02862

Ejemplares similares