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Mechanism and Origins of Stereoselectivity of the Aldol-Tishchenko Reaction of Sulfinimines
[Image: see text] Density functional theory computations have elucidated the mechanism and origins of stereoselectivity in McGlacken’s aldol-Tishchenko reaction for the diastereoselective synthesis of 1,3-amino alcohols using Ellman’s t-butylsulfinimines as chiral auxiliaries. Variations of stereoch...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8279497/ https://www.ncbi.nlm.nih.gov/pubmed/33586983 http://dx.doi.org/10.1021/acs.joc.0c02862 |