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Capillary Ionization and Jumps of Capacitive Energy Stored in Mesopores
[Image: see text] We study ionic liquid–solvent mixtures in slit-shaped nanopores wider than a few ion diameters. Using a continuum theory and generic thermodynamic reasoning, we reveal that such systems can undergo a capillary ionization transition. At this transition, the pores spontaneously ioniz...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2021
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8282200/ https://www.ncbi.nlm.nih.gov/pubmed/34276858 http://dx.doi.org/10.1021/acs.jpcc.1c00624 |