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Routes to High-Performing Ruthenium–Iodide Catalysts for Olefin Metathesis: Ligand Lability Is Key to Efficient Halide Exchange
[Image: see text] Clean, high-yielding routes are described to ruthenium–diiodide catalysts that were recently shown to enable high productivity in olefin metathesis. For the second-generation Grubbs and Hoveyda catalysts (GII: RuCl(2)(H(2)IMes)(PCy(3))(=CHPh); HII: RuCl(2)(H(2)IMes)(=CHAr), Ar = C(...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8289337/ https://www.ncbi.nlm.nih.gov/pubmed/34295013 http://dx.doi.org/10.1021/acs.organomet.1c00253 |