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Role of redox-inactive metals in controlling the redox potential of heterometallic manganese–oxido clusters
Photosystem II (PSII) contains Ca(2+), which is essential to the oxygen-evolving activity of the catalytic Mn(4)CaO(5) complex. Replacement of Ca(2+) with other redox-inactive metals results in a loss/decrease of oxygen-evolving activity. To investigate the role of Ca(2+) in this catalytic reaction,...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Springer Netherlands
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8292285/ https://www.ncbi.nlm.nih.gov/pubmed/34047897 http://dx.doi.org/10.1007/s11120-021-00846-y |