Understanding the mechanism of direct visible-light-activated [2 + 2] cycloadditions mediated by Rh and Ir photocatalysts: combined computational and spectroscopic studies

The mechanism of [2 + 2] cycloadditions activated by visible light and catalyzed by bis-cyclometalated Rh(iii) and Ir(iii) photocatalysts was investigated, combining density functional theory calculations and spectroscopic techniques. Experimental observations show that the Rh-based photocatalyst pr...

Descripción completa

Detalles Bibliográficos
Autores principales: Jung, Hoimin, Hong, Mannkyu, Marchini, Marianna, Villa, Marco, Steinlandt, Philipp S., Huang, Xiaoqiang, Hemming, Marcel, Meggers, Eric, Ceroni, Paola, Park, Jiyong, Baik, Mu-Hyun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8293808/
https://www.ncbi.nlm.nih.gov/pubmed/34349938
http://dx.doi.org/10.1039/d1sc02745j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8293808/
https://www.ncbi.nlm.nih.gov/pubmed/34349938
http://dx.doi.org/10.1039/d1sc02745j

Ejemplares similares