Mechanistic study on the reaction of pinB-BMes(2) with alkynes based on experimental investigation and DFT calculations: gradual change of mechanism depending on the substituent

Transition metal-free direct and base-catalyzed 1,2-diborations of arylacetylenes using pinB-BMes(2) provided a syn/anti-isomeric mixture of diborylalkenes. The kinetic analysis showed that the reaction rate and isomer ratio were affected by reaction conditions and substituents on the aryl ring. DFT...

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Detalles Bibliográficos
Autores principales: Wu, Linlin, Kojima, Chiemi, Lee, Ka-Ho, Morisako, Shogo, Lin, Zhenyang, Yamashita, Makoto
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8293998/
https://www.ncbi.nlm.nih.gov/pubmed/34349954
http://dx.doi.org/10.1039/d1sc02863d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8293998/
https://www.ncbi.nlm.nih.gov/pubmed/34349954
http://dx.doi.org/10.1039/d1sc02863d

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