Cargando…
Mechanistic study on the reaction of pinB-BMes(2) with alkynes based on experimental investigation and DFT calculations: gradual change of mechanism depending on the substituent
Transition metal-free direct and base-catalyzed 1,2-diborations of arylacetylenes using pinB-BMes(2) provided a syn/anti-isomeric mixture of diborylalkenes. The kinetic analysis showed that the reaction rate and isomer ratio were affected by reaction conditions and substituents on the aryl ring. DFT...
| Autores principales: | , , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8293998/ https://www.ncbi.nlm.nih.gov/pubmed/34349954 http://dx.doi.org/10.1039/d1sc02863d |