Ipso-Type Regiocontrolled Benzannulation for the Synthesis of Uniquely Substituted α-Arylnaphthalenes: Application to the First Total Synthesis of Chaihunaphthone

[Image: see text] A distinctive method for synthesizing a variety of multisubstituted α-arylnaphthalenes utilizing novel regiocontrolled ipso-type [4 + 2] benzannulation is presented. Ortho- and para-substituted 1-Ar(1)-1-Ar(2)-2,2-dichlorocyclopropylmethanols (AACM) were transformed to the correspo...

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Detalles Bibliográficos
Autores principales: Moriguchi, Kento, Sasaki, Ryosuke, Morita, Jun-ichi, Kamakura, Yoshinobu, Tanaka, Daisuke, Tanabe, Yoo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8296562/
https://www.ncbi.nlm.nih.gov/pubmed/34308046
http://dx.doi.org/10.1021/acsomega.1c02000

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8296562/
https://www.ncbi.nlm.nih.gov/pubmed/34308046
http://dx.doi.org/10.1021/acsomega.1c02000

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