A Dichotomy in Cross-Coupling Site Selectivity in a Dihalogenated Heteroarene: Influence of Mononuclear Pd, Pd Clusters, and Pd Nanoparticles—the Case for Exploiting Pd Catalyst Speciation

[Image: see text] Site-selective dihalogenated heteroarene cross-coupling with organometallic reagents usually occurs at the halogen proximal to the heteroatom, enabled by intrinsic relative electrophilicity, particularly in strongly polarized systems. An archetypical example is the Suzuki–Miyaura c...

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Detalles Bibliográficos
Autores principales: Scott, Neil W. J., Ford, Mark J., Jeddi, Neda, Eyles, Anthony, Simon, Lauriane, Whitwood, Adrian C., Tanner, Theo, Willans, Charlotte E., Fairlamb, Ian J. S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8297865/
https://www.ncbi.nlm.nih.gov/pubmed/34152135
http://dx.doi.org/10.1021/jacs.1c05294

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8297865/
https://www.ncbi.nlm.nih.gov/pubmed/34152135
http://dx.doi.org/10.1021/jacs.1c05294

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