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Mechanism of Unusual Isosymmetric Order-Disorder Phase Transition in [Dimethylhydrazinium]Mn(HCOO)(3) Hybrid Perovskite Probed by Vibrational Spectroscopy
[DMHy]Mn(HCOO)(3) (DMHy(+) = dimethylhydrazinium cation) is an example of an organic–inorganic hybrid adopting perovskite-like architecture with the largest organic cation used so far in the synthesis of formate-based hybrids. This compound undergoes an unusual isosymmetric phase transition at 240 K...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8303174/ https://www.ncbi.nlm.nih.gov/pubmed/34300914 http://dx.doi.org/10.3390/ma14143984 |