Ni Oxidation State and Ligand Saturation Impact on the Capability of Octaazamacrocyclic Complexes to Bind and Reduce CO(2)

Two 15-membered octaazamacrocyclic nickel(II) complexes are investigated by theoretical methods to shed light on their affinity forwards binding and reducing CO(2). In the first complex (1)[Ni(II)L](0), the octaazamacrocyclic ligand is grossly unsaturated (π-conjugated), while in the second (1)[Ni(I...

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Detalles Bibliográficos
Autores principales: Vénosová, Barbora, Jelemenská, Ingrid, Kožíšek, Jozef, Rapta, Peter, Zalibera, Michal, Novotný, Michal, Arion, Vladimir B., Bučinský, Lukáš
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8307626/
https://www.ncbi.nlm.nih.gov/pubmed/34299414
http://dx.doi.org/10.3390/molecules26144139

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8307626/
https://www.ncbi.nlm.nih.gov/pubmed/34299414
http://dx.doi.org/10.3390/molecules26144139

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