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An intramolecularly self-templated synthesis of macrocycles: self-filling effects on the formation of prismarenes

Ethyl- and propyl-prism[6]arenes are obtained in high yields and in short reaction times, independent of the nature and size of the solvent, in the cyclization of 2,6-dialkoxynaphthalene with paraformaldehyde. PrS[6]Et or PrS[6]nPr adopt, both in solution and in the solid state, a folded cuboid-shap...

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Detalles Bibliográficos
Autores principales: Della Sala, Paolo, Del Regno, Rocco, Di Marino, Luca, Calabrese, Carmela, Palo, Carmine, Talotta, Carmen, Geremia, Silvano, Hickey, Neal, Capobianco, Amedeo, Neri, Placido, Gaeta, Carmine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8317625/
https://www.ncbi.nlm.nih.gov/pubmed/34349965
http://dx.doi.org/10.1039/d1sc02199k