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Ni(0)-promoted activation of C(sp(2))–H and C(sp(2))–O bonds
A dinickel(0)–N(2) complex, stabilized with a rigid acridane-based PNP pincer ligand, was studied for its ability to activate C(sp(2))–H and C(sp(2))–O bonds. Stabilized by a Ni–μ–N(2)–Na(+) interaction, it activates C–H bonds of unfunctionalized arenes, affording nickel–aryl and nickel–hydride prod...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8317657/ https://www.ncbi.nlm.nih.gov/pubmed/34377392 http://dx.doi.org/10.1039/d1sc02210e |