Electrooxidative dearomatization of biaryls: synthesis of tri- and difluoromethylated spiro[5.5]trienones

Radical spirocyclization via dearomatization has emerged as an attractive strategy for the rapid synthesis of structurally diverse spiro molecules. We report the use of electrochemistry to perform an oxidative dearomatization of biaryls leading to tri- and difluoromethylated spiro[5.5]trienones in a...

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Detalles Bibliográficos
Autores principales: Zhang, Yan, Ma, Chanchan, Struwe, Julia, Feng, Jian, Zhu, Gangguo, Ackermann, Lutz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8317667/
https://www.ncbi.nlm.nih.gov/pubmed/34377402
http://dx.doi.org/10.1039/d1sc02682h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8317667/
https://www.ncbi.nlm.nih.gov/pubmed/34377402
http://dx.doi.org/10.1039/d1sc02682h

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