Stereoselective Synthesis of trans-Decalin-Based Spirocarbocycles via Photocyclization of 1,2-Diketones

[Image: see text] Diastereoselective synthesis of the trans-decalin-based α-hydroxyl butanone spirocarbocycles bearing all-carbon quaternary stereogenic centers has been achieved via Norrish–Yang photocyclization of trans-decalin-substituted-2,3-butanediones using daylight. Density functional theory...

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Detalles Bibliográficos
Autores principales: Chen, Sijia, Zhang, Zhongchao, Jiang, Chongguo, Zhao, Chunbo, Luo, Haojie, Huang, Jun, Yang, Zhen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8320103/
https://www.ncbi.nlm.nih.gov/pubmed/34337224
http://dx.doi.org/10.1021/acsomega.1c02054

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8320103/
https://www.ncbi.nlm.nih.gov/pubmed/34337224
http://dx.doi.org/10.1021/acsomega.1c02054

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