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Fast synthesis and redox switching of di- and tetra-substituted bisthioxanthylidene overcrowded alkenes

A rapid and efficient method for the synthesis of overcrowded alkenes using (trimethylsilyl)diazomethane provides a range of substituted bisthioxanthylidenes. We show large conformational redox switching from folded to orthogonal states, which tolerates many substitution patterns. The facile access...

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Detalles Bibliográficos
Autores principales: Corbet, Brian P., Wonink, Marco B. S., Feringa, Ben L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8330637/
https://www.ncbi.nlm.nih.gov/pubmed/34254090
http://dx.doi.org/10.1039/d1cc03098a