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Fast synthesis and redox switching of di- and tetra-substituted bisthioxanthylidene overcrowded alkenes
A rapid and efficient method for the synthesis of overcrowded alkenes using (trimethylsilyl)diazomethane provides a range of substituted bisthioxanthylidenes. We show large conformational redox switching from folded to orthogonal states, which tolerates many substitution patterns. The facile access...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8330637/ https://www.ncbi.nlm.nih.gov/pubmed/34254090 http://dx.doi.org/10.1039/d1cc03098a |