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Direct electrochemical hydrodefluorination of trifluoromethylketones enabled by non-protic conditions

CF(2)H groups are unique due to the combination of their lipophilic and hydrogen bonding properties. The strength of H-bonding is determined by the group to which it is appended. Several functional groups have been explored in this context including O, S, SO and SO(2) to tune the intermolecular inte...

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Detalles Bibliográficos
Autores principales: Box, John R., Atkins, Alexander P., Lennox, Alastair J. J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8336478/
https://www.ncbi.nlm.nih.gov/pubmed/34377412
http://dx.doi.org/10.1039/d1sc01574e