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Structure of the {U(13)} polyoxo cluster U(13)O(8)Cl( x )(MeO)(38–x ) (x = 2.3, MeO = methoxide)

The structure of a new type of polyoxo cluster complex that contains thirteen uranium atoms, {U(13)}, is reported. The complex crystallized from methanol containing tetra­valent uranium (U(IV)) with a basic organic ligand, and was characterized as di­chloridoocta­cosa-μ(2)-methano­lato-octa­kis­(met...

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Detalles Bibliográficos
Autores principales: Fichter, Sebastian, Radoske, Thomas, Ikeda-Ohno, Atsushi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8340969/
https://www.ncbi.nlm.nih.gov/pubmed/34422313
http://dx.doi.org/10.1107/S2056989021007623