Excited States Symmetry Breaking and In-Plane Polarization Cause Chiral Reversal in Diastereomers

In this work, we investigate the electronic transitions and chirality of three isomers of huge conjugated systems: asymmetric diastereomers (MMMM) and two symmetrical diastereomers (PMPM and PPMM). The physical mechanism of flipping has been studied theoretically. The new ribbon-shaped polycyclic ar...

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Detalles Bibliográficos
Autores principales: Wang, Chenglong, Wang, Jingang, Wang, Chunyang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8347323/
https://www.ncbi.nlm.nih.gov/pubmed/34361833
http://dx.doi.org/10.3390/molecules26154680

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8347323/
https://www.ncbi.nlm.nih.gov/pubmed/34361833
http://dx.doi.org/10.3390/molecules26154680

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