Square-Planar Heteroleptic Complexes of α-Diimine-Ni(II)-Catecholate Type: Intramolecular Ligand-to-Ligand Charge Transfer

Two heteroleptic Ni(II) complexes combined the redox-active catecholate and 2,2′- bipyridine ligand platforms were synthesized to observe a photoinduced intramolecular ligand-to-ligand charge transfer (LL’CT, HOMO(catecholate) → LUMO(α-diimine)). A molecular design of compound [Ni(II)(3,6-Cat)(bipy)...

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Detalles Bibliográficos
Autores principales: Pashanova, Kira I., Bitkina, Vladlena O., Yakushev, Ilya A., Arsenyev, Maxim V., Piskunov, Alexandr V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8347615/
https://www.ncbi.nlm.nih.gov/pubmed/34361775
http://dx.doi.org/10.3390/molecules26154622

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8347615/
https://www.ncbi.nlm.nih.gov/pubmed/34361775
http://dx.doi.org/10.3390/molecules26154622

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