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Transition-Metal-Catalyzed Diarylation of Isocyanides with Triarylbismuthines for the Selective Synthesis of Imine Derivatives

The transition-metal-catalyzed diarylation of isocyanides with triarylbismuthines was investigated in detail, and rhodium catalysts such as [RhCl(nbd)](2) were found to selectively afford N-alkyl diaryl ketimines. On the other hand, palladium-catalyzed diarylation proceeded with the incorporation of...

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Detalles Bibliográficos
Autores principales: Kodama, Shintaro, Yamamoto, Yuki, Kobiki, Yohsuke, Matsubara, Hitomi, Tran, Cong Chi, Kawaguchi, Shin-ichi, Nomoto, Akihiro, Ogawa, Akiya
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8348920/
https://www.ncbi.nlm.nih.gov/pubmed/34361465
http://dx.doi.org/10.3390/ma14154271