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Intramolecular Hydrogen Atom Transfer Induced 1,2-Migration of Boronate Complexes
[Image: see text] Radical α-C-H functionalization of alk-5-enyl boronic esters with concomitant functionalization of the alkene moiety is reported. These cascades comprise perfluoroalkyl radical addition to the alkene moiety of a boronate complex, intramolecular hydrogen atom transfer (HAT), single...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2021
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8353630/ https://www.ncbi.nlm.nih.gov/pubmed/34260254 http://dx.doi.org/10.1021/acs.orglett.1c01998 |