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Intramolecular Hydrogen Atom Transfer Induced 1,2-Migration of Boronate Complexes

[Image: see text] Radical α-C-H functionalization of alk-5-enyl boronic esters with concomitant functionalization of the alkene moiety is reported. These cascades comprise perfluoroalkyl radical addition to the alkene moiety of a boronate complex, intramolecular hydrogen atom transfer (HAT), single...

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Detalles Bibliográficos
Autores principales: Wang, Dinghai, Jana, Kalipada, Studer, Armido
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8353630/
https://www.ncbi.nlm.nih.gov/pubmed/34260254
http://dx.doi.org/10.1021/acs.orglett.1c01998