On the Origin of E-Selectivity in the Ring-Opening Metathesis Polymerization with Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes

[Image: see text] The understanding and control of stereoselectivity is a central aspect in ring-opening metathesis polymerization (ROMP). Herein, we report detailed quantum chemical studies on the reaction mechanism of E-selective ROMP of norborn-2-ene (NBE) with Mo(N-2,6-Me(2)-C(6)H(3))(CHCMe(3))(...

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Detalles Bibliográficos
Autores principales: Podewitz, Maren, Sen, Suman, Buchmeiser, Michael R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8356225/
https://www.ncbi.nlm.nih.gov/pubmed/34393318
http://dx.doi.org/10.1021/acs.organomet.1c00229

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8356225/
https://www.ncbi.nlm.nih.gov/pubmed/34393318
http://dx.doi.org/10.1021/acs.organomet.1c00229

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