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Free three-dimensional carborane carbanions

Carbon atom functionalization via generation of carbanions is the cornerstone of carborane chemistry. In this work, we report the synthesis and structural characterization of free ortho-carboranyl [C(2)B(10)H(11)](−), a three-dimensional inorganic analog of the elusive phenyl anion that features a “...

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Detalles Bibliográficos
Autores principales: Jayaweera, H. D. A. Chathumal, Rahman, Md. Mamdudur, Pellechia, Perry J., Smith, Mark D., Peryshkov, Dmitry V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8356735/
https://www.ncbi.nlm.nih.gov/pubmed/34447536
http://dx.doi.org/10.1039/d1sc02252k