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Synthesis and enantioseparation of chiral Au(13) nanoclusters protected by bis-N-heterocyclic carbene ligands
A series of chiral Au(13) nanoclusters were synthesized via the direct reduction of achiral dinuclear Au(i) halide complexes ligated by ortho-xylyl-linked bis-N-heterocyclic carbene (NHC) ligands. A broad range of functional groups are tolerated as wingtip substituents, allowing for the synthesis of...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8356741/ https://www.ncbi.nlm.nih.gov/pubmed/34447535 http://dx.doi.org/10.1039/d1sc03076k |