Cargando…

Synthesis and enantioseparation of chiral Au(13) nanoclusters protected by bis-N-heterocyclic carbene ligands

A series of chiral Au(13) nanoclusters were synthesized via the direct reduction of achiral dinuclear Au(i) halide complexes ligated by ortho-xylyl-linked bis-N-heterocyclic carbene (NHC) ligands. A broad range of functional groups are tolerated as wingtip substituents, allowing for the synthesis of...

Descripción completa

Detalles Bibliográficos
Autores principales: Yi, Hong, Osten, Kimberly M., Levchenko, Tetyana I., Veinot, Alex J., Aramaki, Yoshitaka, Ooi, Takashi, Nambo, Masakazu, Crudden, Cathleen M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8356741/
https://www.ncbi.nlm.nih.gov/pubmed/34447535
http://dx.doi.org/10.1039/d1sc03076k