Nickel-mediated N–N bond formation and N(2)O liberation via nitrogen oxyanion reduction

The syntheses of (DIM)Ni(NO(3))(2) and (DIM)Ni(NO(2))(2), where DIM is a 1,4-diazadiene bidentate donor, are reported to enable testing of bis boryl reduced N-heterocycles for their ability to carry out stepwise deoxygenation of coordinated nitrate and nitrite, forming O(Bpin)(2). Single deoxygenati...

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Detalles Bibliográficos
Autores principales: Beagan, Daniel M., Cabelof, Alyssa C., Pink, Maren, Carta, Veronica, Gao, Xinfeng, Caulton, Kenneth G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8356809/
https://www.ncbi.nlm.nih.gov/pubmed/34447560
http://dx.doi.org/10.1039/d1sc02846d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8356809/
https://www.ncbi.nlm.nih.gov/pubmed/34447560
http://dx.doi.org/10.1039/d1sc02846d

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