Cargando…
Nickel-mediated N–N bond formation and N(2)O liberation via nitrogen oxyanion reduction
The syntheses of (DIM)Ni(NO(3))(2) and (DIM)Ni(NO(2))(2), where DIM is a 1,4-diazadiene bidentate donor, are reported to enable testing of bis boryl reduced N-heterocycles for their ability to carry out stepwise deoxygenation of coordinated nitrate and nitrite, forming O(Bpin)(2). Single deoxygenati...
| Autores principales: | , , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8356809/ https://www.ncbi.nlm.nih.gov/pubmed/34447560 http://dx.doi.org/10.1039/d1sc02846d |