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Palladium-catalyzed asymmetric allylic alkylation (AAA) with alkyl sulfones as nucleophiles
An efficient palladium-catalyzed AAA reaction with a simple α-sulfonyl carbon anion as nucleophiles is presented for the first time. Allyl fluorides are used as superior precursors for the generation of π-allyl complexes that upon ionization liberate fluoride anions for activation of silylated nucle...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8356815/ https://www.ncbi.nlm.nih.gov/pubmed/34447546 http://dx.doi.org/10.1039/d1sc02599f |