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Structural and Electronic Properties of Iron(0) PNP Pincer Complexes

In the present work we have prepared and fully characterized several Fe(0) complexes of the type [Fe(PNP)(CO)(2)] treating Fe(II) complexes [Fe(PNP)(Cl)(2)] with KC(8) in the presence of carbon monoxide. While complexes [Fe(PNP(NMe)‐iPr)(CO)(2)], [Fe(PNP(NEt)‐iPr)(CO)(2)] adopt a trigonal bipyramida...

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Detalles Bibliográficos
Autores principales: Glatz, Mathias, Gorgas, Nikolaus, Stöger, Berthold, Pittenauer, Ernst, Ferreira, Liliana, Veiros, Luis F., Calhorda, Maria José, Kirchner, Karl
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8360027/
https://www.ncbi.nlm.nih.gov/pubmed/34413550
http://dx.doi.org/10.1002/zaac.202100015