Phosphetes via Transition Metal Free Ring Closure – Taking the Proper Turn at a Thermodynamic Crossing

A transition metal free route to phosphetes featuring an exocyclic alkene unit is presented. In this approach phosphanides are added to a variety of diynes generating phosphaallylic intermediates which depending on the reaction conditions transform either to phosphetes or the corresponding phosphole...

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Detalles Bibliográficos
Autores principales: Roesler, Fabian, Kovács, Máté, Bruhn, Clemens, Kelemen, Zsolt, Pietschnig, Rudolf
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8361766/
https://www.ncbi.nlm.nih.gov/pubmed/33971050
http://dx.doi.org/10.1002/chem.202101298

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8361766/
https://www.ncbi.nlm.nih.gov/pubmed/33971050
http://dx.doi.org/10.1002/chem.202101298

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