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Bis(4‐benzhydryl‐benzoxazol‐2‐yl)methane – from a Bulky NacNac Alternative to a Trianion in Alkali Metal Complexes

A novel sterically demanding bis(4‐benzhydryl‐benzoxazol‐2‐yl)methane ligand 6 ((4−BzhH2)BoxCH(2)) was gained in a straightforward six‐step synthesis. Starting from this ligand monomeric [M((4‐BzhH2)BoxCH)] (M=Na (7), K (8(1) )) and dimeric [{M((4‐BzhH2)BoxCH)}(2)] (M=K (8(2) ), Rb (9), Cs (10)) alk...

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Detalles Bibliográficos
Autores principales: Kretsch, Johannes, Kreyenschmidt, Anne‐Kathrin, Schillmöller, Timo, Lõkov, Märt, Herbst‐Irmer, Regine, Leito, Ivo, Stalke, Dietmar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8361911/
https://www.ncbi.nlm.nih.gov/pubmed/34036637
http://dx.doi.org/10.1002/chem.202100616