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Cleavage of the N≡N Triple Bond and Unpredicted Formation of the Cyclic 1,3‐Diaza‐2,4‐Diborete (FB)(2)N(2) from N(2) and Fluoroborylene BF
A complete cleavage of the triple bond of N(2) by fluoroborylene (:BF) was achieved in a low‐temperature N(2) matrix by the formation of the four‐membered heterocycle FB(μ‐N)(2)BF, which lacks a trans‐annular N−N bond. Additionally, the linear complex FB=N−N=BF and cyclic FB(η (2)‐N(2)) were formed....
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8361949/ https://www.ncbi.nlm.nih.gov/pubmed/34114317 http://dx.doi.org/10.1002/anie.202106984 |