Thiols Act as Methyl Traps in the Biocatalytic Demethylation of Guaiacol Derivatives

Demethylating methyl phenyl ethers is challenging, especially when the products are catechol derivatives prone to follow‐up reactions. For biocatalytic demethylation, monooxygenases have previously been described requiring molecular oxygen which may cause oxidative side reactions. Here we show that...

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Detalles Bibliográficos
Autores principales: Pompei, Simona, Grimm, Christopher, Schiller, Christine, Schober, Lukas, Kroutil, Wolfgang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8361964/
https://www.ncbi.nlm.nih.gov/pubmed/34057803
http://dx.doi.org/10.1002/anie.202104278

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8361964/
https://www.ncbi.nlm.nih.gov/pubmed/34057803
http://dx.doi.org/10.1002/anie.202104278

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