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Thiols Act as Methyl Traps in the Biocatalytic Demethylation of Guaiacol Derivatives
Demethylating methyl phenyl ethers is challenging, especially when the products are catechol derivatives prone to follow‐up reactions. For biocatalytic demethylation, monooxygenases have previously been described requiring molecular oxygen which may cause oxidative side reactions. Here we show that...
Autores principales: | Pompei, Simona, Grimm, Christopher, Schiller, Christine, Schober, Lukas, Kroutil, Wolfgang |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8361964/ https://www.ncbi.nlm.nih.gov/pubmed/34057803 http://dx.doi.org/10.1002/anie.202104278 |
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