Electrocatalytic Activation of Donor–Acceptor Cyclopropanes and Cyclobutanes: An Alternative C(sp(3))−C(sp(3)) Cleavage Mode

We describe the first electrochemical activation of D–A cyclopropanes and D–A cyclobutanes leading after C(sp(3))−C(sp(3)) cleavage to the formation of highly reactive radical cations. This concept is utilized to formally insert molecular oxygen after direct or DDQ‐assisted anodic oxidation of the s...

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Detalles Bibliográficos
Autores principales: Kolb, Simon, Petzold, Martin, Brandt, Felix, Jones, Peter G., Jacob, Christoph R., Werz, Daniel B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362004/
https://www.ncbi.nlm.nih.gov/pubmed/33890714
http://dx.doi.org/10.1002/anie.202101477

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362004/
https://www.ncbi.nlm.nih.gov/pubmed/33890714
http://dx.doi.org/10.1002/anie.202101477

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