Tricyanidoferrates(−IV) and Ruthenates(−IV) with Non‐Innocent Cyanido Ligands

Exceptionally electron‐rich, nearly trigonal‐planar tricyanidometalate anions [Fe(CN)(3)](7−) and [Ru(CN)(3)](7−) were stabilized in LiSr(3)[Fe(CN)(3)] and AE(3.5)[M(CN)(3)] (AE=Sr, Ba; M=Fe, Ru). They are the first examples of group 8 elements with the oxidation state of −IV. Microcrystalline powde...

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Detalles Bibliográficos
Autores principales: Jach, Franziska, Wagner, Frank R., Amber, Zeeshan H., Rüsing, Michael, Hunger, Jens, Prots, Yurii, Kaiser, Martin, Bobnar, Matej, Jesche, Anton, Eng, Lukas M., Ruck, Michael, Höhn, Peter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362014/
https://www.ncbi.nlm.nih.gov/pubmed/33938602
http://dx.doi.org/10.1002/anie.202103268

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362014/
https://www.ncbi.nlm.nih.gov/pubmed/33938602
http://dx.doi.org/10.1002/anie.202103268

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