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Facilitating the Ferration of Aromatic Substrates through Intramolecular Sodium Mediation

Exploiting cooperative effects between Na and Fe(II) centres present in tris(amide) ferrate complexes has led to the chemoselective ferration of pentafluorobenzene, benzene, toluene, anisole, and pyridine being realised at room temperature. The importance of this bimetallic partnership is demonstrat...

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Detalles Bibliográficos
Autores principales: Maddock, Lewis C. H., Mu, Manting, Kennedy, Alan R., García‐Melchor, Max, Hevia, Eva
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362017/
https://www.ncbi.nlm.nih.gov/pubmed/33950575
http://dx.doi.org/10.1002/anie.202104275