Dioxygen Activation and Pyrrole α‐Cleavage with Calix[4]pyrrolato Aluminates: Enzyme Model by Structural Constraint

The present work describes the reaction of triplet dioxygen with the porphyrinogenic calix[4]pyrrolato aluminates to alkylperoxido aluminates in high selectivity. Multiconfigurational quantum chemical computations disclose the mechanism for this spin‐forbidden process. Despite a negligible spin–orbi...

Descripción completa

Detalles Bibliográficos
Autores principales: Sigmund, Lukas Maximilian, Ehlert, Christopher, Enders, Markus, Graf, Jürgen, Gryn'ova, Ganna, Greb, Lutz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362023/
https://www.ncbi.nlm.nih.gov/pubmed/33955154
http://dx.doi.org/10.1002/anie.202104916

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362023/
https://www.ncbi.nlm.nih.gov/pubmed/33955154
http://dx.doi.org/10.1002/anie.202104916

Ejemplares similares