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Dioxygen Activation and Pyrrole α‐Cleavage with Calix[4]pyrrolato Aluminates: Enzyme Model by Structural Constraint

The present work describes the reaction of triplet dioxygen with the porphyrinogenic calix[4]pyrrolato aluminates to alkylperoxido aluminates in high selectivity. Multiconfigurational quantum chemical computations disclose the mechanism for this spin‐forbidden process. Despite a negligible spin–orbi...

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Detalles Bibliográficos
Autores principales:	Sigmund, Lukas Maximilian, Ehlert, Christopher, Enders, Markus, Graf, Jürgen, Gryn'ova, Ganna, Greb, Lutz
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362023/ https://www.ncbi.nlm.nih.gov/pubmed/33955154 http://dx.doi.org/10.1002/anie.202104916

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