Relevance of π‐Backbonding for the Reactivity of Electrophilic Anions [B(12)X(11)](−) (X=F, Cl, Br, I, CN)

Electrophilic anions of type [B(12)X(11)](−) posses a vacant positive boron binding site within the anion. In a comparatitve experimental and theoretical study, the reactivity of [B(12)X(11)](−) with X=F, Cl, Br, I, CN is characterized towards different nucleophiles: (i) noble gases (NGs) as σ‐donor...

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Detalles Bibliográficos
Autores principales: Mayer, Martin, Rohdenburg, Markus, Kawa, Sebastian, Horn, Francine, Knorke, Harald, Jenne, Carsten, Tonner, Ralf, Asmis, Knut R., Warneke, Jonas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362024/
https://www.ncbi.nlm.nih.gov/pubmed/34014012
http://dx.doi.org/10.1002/chem.202100949

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362024/
https://www.ncbi.nlm.nih.gov/pubmed/34014012
http://dx.doi.org/10.1002/chem.202100949

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