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Relevance of π‐Backbonding for the Reactivity of Electrophilic Anions [B(12)X(11)](−) (X=F, Cl, Br, I, CN)

Electrophilic anions of type [B(12)X(11)](−) posses a vacant positive boron binding site within the anion. In a comparatitve experimental and theoretical study, the reactivity of [B(12)X(11)](−) with X=F, Cl, Br, I, CN is characterized towards different nucleophiles: (i) noble gases (NGs) as σ‐donor...

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Detalles Bibliográficos
Autores principales:	Mayer, Martin, Rohdenburg, Markus, Kawa, Sebastian, Horn, Francine, Knorke, Harald, Jenne, Carsten, Tonner, Ralf, Asmis, Knut R., Warneke, Jonas
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362024/ https://www.ncbi.nlm.nih.gov/pubmed/34014012 http://dx.doi.org/10.1002/chem.202100949

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