Coexistence of Two Different Distorted Octahedral [MnF(6)](3−) Sites in K(3)[MnF(6)]: Manifestation in Spectroscopy and Magnetism

As a consequence of the static Jahn‐Teller effect of the (5)E ground state of Mn(III) in cubic structures with octahedral parent geometries, their octahedral coordination spheres become distorted. In the case of six fluorido ligands, [MnF(6)](3−) anions with two longer and four shorter Mn−F bonds ma...

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Detalles Bibliográficos
Autores principales: Stoll, Christiane, Atanasov, Mihail, Bandemehr, Jascha, Neese, Frank, Pietzonka, Clemens, Kraus, Florian, Karttunen, Antti J., Seibald, Markus, Heymann, Gunter, Huppertz, Hubert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362050/
https://www.ncbi.nlm.nih.gov/pubmed/33830547
http://dx.doi.org/10.1002/chem.202005496

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8362050/
https://www.ncbi.nlm.nih.gov/pubmed/33830547
http://dx.doi.org/10.1002/chem.202005496

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